基本情况
肖晶,男,1987年生,博士,副教授,硕士生导师。2016年博士毕业于湖南大学,2017年至2018年在日本产业技术综合研究所从事博士后研究工作。中国化学会会员,现为理论有机化学与功能分子教育部重点实验室专职科研人员。主要研究方向为有机合成方法学(绿色磷化学,自由基反应以及绿色还原反应等),近年来主持国家自然科学基金青年项目1项、省部级项目1项、重点实验室开放课题1项,企业横向课题1项。在《Org.Lett.》、《Chem. Commun.》、《Adv. Synth. Catal.》以及《J. Org. Chem.》等国际主流期刊发表多篇论文,授权发明专利2项。
主持课题
[1] 国家自然科学青年基金,铜催化C-H键活化与自由基介导构筑C-C键的反应研究(21703061),26万,2018.01-2020.12
[2] 湖南省自然科学青年基金,基于过渡金属催化C-O键活化的炔烃加成反应研究(2017JJ3081),5万,2017.01-2019.12
[3] 横向课题,基于亚磷酸的有机还原反应方法开发(D121L4), 20 万,2021.12-2023.12
代表性论文
[1] Jing Xiao*, Fengzhe Guo, Yinfeng Li, Fangshao Li, Qiang Li, Zi-Long Tang, Iodine Promoted Conversion of Esters to Nitriles and Ketones under Metal-Free Conditions, J. Org. Chem ., 2021, 86, 2028–2035.
[2] Fang Lv, Jing Xiao*, Junchun Xiang, Fengzhe Guo, Zi-Long Tang, Li-Biao Han*, Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H3PO3/I2, J. Org. Chem ., 2021, 86, 3081–3088.
[3] Jing Xiao*, Fangshao Li, Ting Zhong, Xiaofang Wu, Fengzhe Guo, Qiang Li, Zi-Long Tang, Copper-catalyzed Radical Oxidative C(sp3)-H/C(sp3)-H Cross-coupling Between Arylacetonitriles and Benzylic Compounds, Tetrahedron , 2020, 76, 131621.
[4] Jing Xiao, Qiang Li, Ruwei Shen*, Shigeru Shimada, and Li-Biao Han*, Phosphonium Phenolate Zwitterion vs Phosphonium Ylide: Synthesis, Characterization and Reactivity Study of a Trimethylphosphonium Phenolate Zwitterion. Adv. Synth. Catal. , 2019, 361, 5715–5720.
[5] Jing Xiao*, Yonghao Ma, Xiaofang Wu, Jing Gao, Zilong Tang and Li-Biao Han*, Phosphonic Acid Mediated Practical Dehalogenation and Benzylation with Benzyl Halides. RSC Adv. , 2019, 9, 22343–22347.
[6] Jing Xiao and Li-Biao Han*, Ready Access to Organoiodides: Practical Hydroiodination and Doubleiodination of Carbon-Carbon Unsaturated Bonds with I2. Tetrahedron , 2019, 75, 3510–3515.
[7] Jing Xiao, Jia Yang, Tieqiao Chen*, Li-Biao Han*, Nickel-Catalyzed α-Benzylation of Arylacetonitriles via C-O Activation. Adv. Synth. Catal. , 2016, 358, 816–819.
[8] Jing Xiao, Jia Yang, Tieqiao Chen*, Li-Biao Han*, Nickel-Catalyzed Synthesis of (E)-Olefins from Benzylic Alcohol Derivatives and Arylacetonitriles via C-O Activation. Chem. Commun. , 2016, 52, 2157–2160.
[9] Jing, Xiao, Tieqiao Chen*, Li-Biao Han*, Nickel-Catalyzed Direct C-H/C-O Cross Couplings Generating Fluorobenzenes and Heteroarenes. Org. Lett. , 2015, 17, 812–815.
[10] Jing Xiao, Qiang Li, Tieqiao Chen*, Li-Biao Han*, Copper-mediated Selective Aerobic Oxidative C3-cyanation of Indoles with DMF. Tetrahedron Lett. , 2015, 56, 5937–5940.
[11] Jing Xiao, Jia Yang, Tieqiao Chen*, Li-Biao Han*, Nickel-catalyzed α-benzylation of sulfones with esters via C−O activation. RSC Adv. , 2016, 6, 42656–42659.
[12] Jia Yang, Jing Xiao (Contributed equally), Tieqiao Chen*, Li-Biao Han*, Nickel-catalyzed phosphorylation of phenol derivatives via C−O/P−H cross-coupling. J. Org. Chem. , 2016, 81, 3911–3916.